PSG were knocked out by Barcelona two years ago in the quarter finals and will be hoping to take some kind of revenge on the Catalan team.
The French Champions other opponents Group F include Dutch Champions Ajax and Cypriot team Apoel.
France's other side in the Champions League Monaco were paired with Benfica, , Zenit St Petersburg and Bayer Leverkusen.
This was the draw in full:
Group A: Atletico Madrid, Juventus, Olympiacos, Malmo
Group B: Real Madrid, Basel, Liverpool, Ludogorets
Group C: Benfica, Zenit, Bayer Leverkusen, Monaco
Group D: Arsenal, Borussia Dortmund, Galatasaray, Anderlecht
Group E: Bayern Munich, Manchester City, CSKA Moscow, Roma
Group F: Barcelona, PSG, Ajax, Apoel
Group G: Chelsea, Schalke, Sporting Lisbon, Maribor
Group H: Porto, Shakhtar Donetsk, Athletic Bilbao, Bate Borisov